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001 978-3-658-08796-8
003 DE-He213
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008 150211s2015 gw | s |||| 0|eng d
020 _a9783658087968
_9978-3-658-08796-8
024 7 _a10.1007/978-3-658-08796-8
_2doi
050 4 _aQD146-197
072 7 _aPNK
_2bicssc
072 7 _aSCI013030
_2bisacsh
072 7 _aPNK
_2thema
082 0 4 _a546
_223
100 1 _aHerrmann, Sven.
_eauthor.
_4aut
_4http://id.loc.gov/vocabulary/relators/aut
_927041
245 1 0 _aNew Synthetic Routes to Polyoxometalate Containing Ionic Liquids
_h[electronic resource] :
_bAn Investigation of their Properties /
_cby Sven Herrmann.
250 _a1st ed. 2015.
264 1 _aWiesbaden :
_bSpringer Fachmedien Wiesbaden :
_bImprint: Springer Spektrum,
_c2015.
300 _aXXI, 122 p. 61 illus.
_bonline resource.
336 _atext
_btxt
_2rdacontent
337 _acomputer
_bc
_2rdamedia
338 _aonline resource
_bcr
_2rdacarrier
347 _atext file
_bPDF
_2rda
490 1 _aBestMasters,
_x2625-3577
505 0 _aPolyoxometlates and Ionic Liquids in General -- POM-Ils as New Class of Compounds -- Synthesis and Characterization of POM-ILs -- Reactivity Towards Azide and Carbonmonoxide.
520 _aIn his Master project Sven Herrmann for the first time carried out fundamental investigations into the development of polyoxometalate based ionic liquids (POM-ILs). The POM-ILs were obtained by charge balancing inorganic polyoxometalate (POM) anions with sterically demanding tetraalkylammonium or tetraalkylphosphonium cations. By functionalization of lacunary Keggin clusters with 3d-transition metals and charge balancing with tetraalkylammonium cations of differing chain length, a model system for the correlation of the molecular structure with macroscopic materials properties was obtained. In a systematic approach the syntheses via self-aggregation is presented. Analytic methods comprise UV-Vis, FTIR, NMR, EPR and Mößbauer spectroscopy. For determination of the materials properties TGA and DSC were carried out and rheological studies shed light onto the flow characteristics of the highly viscous materials.  Contents Polyoxometlates and Ionic Liquids in General POM-Ils as New Class of Compounds Synthesis and Characterization of POM-ILs Reactivity Towards Azide and Carbonmonoxide  Target Groups Researchers and students in the field of chemistry Practitioners in this area  The Author Sven Herrmann obtained his Masters degree at the University of Erlangen-Nürnberg. He then joined the working group of Prof. Carsten Streb in the inorganic department at the University of Ulm to work on his PhD thesis that targets the development of polyoxometalate based ionic liquids (POM-ILs).
650 0 _aInorganic chemistry.
_927042
650 0 _aCatalysis.
_927043
650 0 _aChemical engineering.
_927044
650 1 4 _aInorganic Chemistry.
_0https://scigraph.springernature.com/ontologies/product-market-codes/C16008
_927045
650 2 4 _aCatalysis.
_0https://scigraph.springernature.com/ontologies/product-market-codes/C29000
_927043
650 2 4 _aIndustrial Chemistry/Chemical Engineering.
_0https://scigraph.springernature.com/ontologies/product-market-codes/C27000
_927046
710 2 _aSpringerLink (Online service)
_927047
773 0 _tSpringer Nature eBook
776 0 8 _iPrinted edition:
_z9783658087975
776 0 8 _iPrinted edition:
_z9783658087951
830 0 _aBestMasters,
_x2625-3577
_927048
856 4 0 _uhttps://doi.org/10.1007/978-3-658-08796-8
912 _aZDB-2-BHS
912 _aZDB-2-SXBP
999 _c182138
_d182138